Temperature dependence of the corrole tautomerization rate

Abstract

The experimental data, consisting of the total fluorescence spectra intensities and fluorescence quantum yields measured in the temperature range from 265 to 338 К are satisfactory reproduced with the theoretical solution of the above described system of equations. The theoretical temperature dependence of the NH tautomerization rate in the lowest excited singlet state fits the experimental one. The probability of the tautomerization in the lowest triplet state is defined.