Please use this identifier to cite or link to this item: https://elib.belstu.by/handle/123456789/36969
Title: Surface and corrosion properties of AA6063-T5 aluminum alloy in molybdate-containing sodium chloride solutions
Authors: Kharitonov, Dmitry S.
Dobrydena, Illia
Sefer, Birhan
Ryl, Jacek
Wrzesińska, Angelika
Makarova, Irina V.
Bobowska, Izabela
Kurilo, Irina I.
Claesson, Per M.
Keywords: aluminum
molybdate inhibitor
corrosion of metallic materials
corrosion inhibition
corrosion properties
алюминиевые сплавы
коррозия металлов
коррозионные свойства
ингибирование коррозии
Issue Date: 2020
Citation: Surface and corrosion properties of AA6063-T5 aluminum alloy in molybdate-containing sodium chloride solutions / Dmitry S. Kharitonov [et al.] // Corrosion Science. - 2020. - Vol. 171. - № 108658
Description: Corrosion properties of aluminum alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic measurements demonstrated that the formed surface layer consists of mixed Mo(VI, V, IV) species. This layer provided inhibition with an efficiency of ∼90% after 4 h of exposure. High efficacy of ∼70% was achieved even after one week of exposure. A two-step oxidation-reduction mechanism of corrosion inhibition by aqueous molybdates was proposed.
URI: https://elib.belstu.by/handle/123456789/36969
Appears in Collections:Публикации в зарубежных изданиях




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